Department of Chemistry, Shiraz University, Shiraz, I.R. IRAN
10.30492/ijcce.1993.10926
Abstract
An efficient synthesis of the 1-hydroxy-2-(prop-2'-enyl)9-anthrone is described. Selective nitration of anthraquinone, reduction to the corresponding amine, diazotization and treatment by sulfuric acid solution afforded the 1-hydroxy-9,10-anthraquinone in good yield as the key intermediate. Reaction with allyl bromide/K2CO3 and subsequent selective reduction accompanied by a Claisen rearrangement produced the title compound in high yield.
Sharghi, H., Tamaddon, F., & Rezaie, R. (1993). Synthesis of 1-Hydroxy-2-(Prop-2'-Enyl) 9-Antrone. Iranian Journal of Chemistry and Chemical Engineering, 12(1), 1-7. doi: 10.30492/ijcce.1993.10926
MLA
Hashem Sharghi; Fatemeh Tamaddon; Ramin Rezaie. "Synthesis of 1-Hydroxy-2-(Prop-2'-Enyl) 9-Antrone". Iranian Journal of Chemistry and Chemical Engineering, 12, 1, 1993, 1-7. doi: 10.30492/ijcce.1993.10926
HARVARD
Sharghi, H., Tamaddon, F., Rezaie, R. (1993). 'Synthesis of 1-Hydroxy-2-(Prop-2'-Enyl) 9-Antrone', Iranian Journal of Chemistry and Chemical Engineering, 12(1), pp. 1-7. doi: 10.30492/ijcce.1993.10926
VANCOUVER
Sharghi, H., Tamaddon, F., Rezaie, R. Synthesis of 1-Hydroxy-2-(Prop-2'-Enyl) 9-Antrone. Iranian Journal of Chemistry and Chemical Engineering, 1993; 12(1): 1-7. doi: 10.30492/ijcce.1993.10926
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