Cadmium Removal from Aqueous Solutions Using Saxaul Tree Ash

Document Type : Research Article

Authors

1 Health Center of Zabol, Zabol University of Medical Sciences, Zabol, I.R. IRAN

2 Department of Environmental Helth, Zabol University of Medical Sciences, Zabol I.R. IRAN

3 Department of Environmental Health Engineering, Gonabad University of Medical Sciences, Gonabad, I.R. IRAN

Abstract

Cadmium can be found in wastewater in high concentrations and can cause dangerous effect on aqueous environment and human health. At present, many methods have been used to heavy metals removal. Among this clean up techniques, adsorption techniques by using low-cost adsorbent are more considerable. In this study, batch adsorption experiments were conducted for removal of cadmium ions from aqueous solutions by using saxaul tree ash as a low-cost adsorbent. The batch experiments were conducted in various conditions as follows: pH (3 to 11), adsorbent dose (0.5 to 6 g/L) g, contact time (15 to 210 min), and initial cadmium concentration (5-50 mg/L). Based on the results, pH=5 with an adsorbent dose of 4 g/L with a 75 min contact time were found to be the optimum for adsorption of cadmium on saxaul tree ash. Also, the results showed that adsorption efficiency is decreased with increase in initial concentrations of cadmium. The isotherm experiments showed that Freundlich model satisfactorily represents the proportional fitting. Therefore, base on the results of this study, saxaul tree ash can be used for efficient removal of cadmium ions from aqueous solution.

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[1] Gupta V.K., Jain C., Ali I., Sharma M.,  Saini V., Removal of Cadmium and Nickel from Wastewater Using Bagasse Fly Ash—a Sugar Industry Waste, Water Res., 37(16): 4038-4044 (2003).
[2] Karaoğlu M.H., Zor Ş.,  Uğurlu M., Biosorption of
Cr (III) from Solutions Using Vineyard Pruning Waste
, Chem. Eng. J., 159(1): 98-106 (2010).
[3] Taty-Costodes V.C., Fauduet H., Porte C., Delacroix A., Removal of Cd (II) and Pb (II) Ions, from Qqueous Solutions, by Adsorption onto Sawdust of Pinus Sylvestris, J. Hazard. Mater., 105(1): 121-142 (2003).
 
[4] Shadborestan A., Khaksar E., Shokrzadeh M.,  Taghavi M., Cadmium, Lead and Chromium Contents in Rice (Champa) Produced in the Mobarakeh County in 2009, J Mazand Univ Med Sci, 23(Suppl-2): 122-127 (2013).
[5] Saifuddin M.,  Kumaran P., Removal of Heavy Metal from Industrial Wastewater Using Chitosan Coated Oil Palm Shell Charcoal, Electron. J. Biotechnol., 8(1): 43-53 (2005).
[6] Kazemipour M., Ansari M., Tajrobehkar S., Majdzadeh M.,  Kermani H.R., Removal of Lead, Cadmium, Zinc, and Copper from Industrial Wastewater by Carbon Developed from Walnut, Hazelnut, Almond, Pistachio Shell, and Apricot Stone, J. Hazard. Mater., 150(2): 322-327 (2008).
[7] Garg U., Kaur M., Jawa G., Sud D.,  Garg V., Removal of Cadmium (II) from Aqueous Solutions by Adsorption on Agricultural Waste Biomass,
J. Hazard. Mater., 154(1): 1149-1157 (2008).
[8] Zazouli M.A., Yousefi Z., Taghavi M., Akbari-adergani B., Cherati J.Y., Cadmium Removal from Aqueous Solutions using L-cysteine Functionalized Single-Walled Carbon Nanotubes, J. Mazand. Univ. Med. Sci., 23(98): 37-47 (2013).
[9] Pino G.H., de Mesquita L.M.S., Torem M.L., 
Pinto G.A.S., Biosorption of Cadmium by Green Coconut Shell Powder, Miner. Eng., 19(5): 380-387 (2006).
[10] Luna A.S., Costa A.L., da Costa A.C.A.,  Henriques C.A., Competitive Biosorption of Cadmium (II) and Zinc (II) Ions from Binary Systems by Sargassum Filipendula, Bioresour. Technol., 101(14): 5104-5111 (2010).
[12] Baik W., Bae J., Cho K.,  Hartmeier W., Biosorption of Heavy Metals Using Whole Mold Mycelia and Parts Thereof, Bioresour. Technol., 81(3): 167-170 (2002).
[13] Pandey P.K., Verma Y., Choubey S., Pandey M.,  Chandrasekhar K., Biosorptive Removal of Cadmium from Contaminated Groundwater and Industrial Effluents, Bioresour. Technol., 99(10): 4420-4427 (2008).
[14] Boparai H.K., Joseph M., O’Carroll D.M., Kinetics and Thermodynamics of Cadmium Ion Removal by Adsorption onto Nano Zerovalent Iron Particles,
J. Hazard. Mater.
, 186(1): 458-465 (2011).
[15] World Health Organization, "Guidelines for Drinking-Water Quality: Recommendations", Vol. 1. World Health Organization (2004).
[16] Wang F.Y., Wang H., Ma J.W., Adsorption of Cadmium (II) Ions from Aqueous Solution by a New Low-Cost Adsorbent—Bamboo Charcoal, J. Hazard. Mater., 177(1): 300-306 (2010).
[17] Choi J., Kim S., Noh S., Oh S.,  Kim W., Adsorption Behaviors of Nano-Sized ETS-10 and Al-Substituted-ETAS-10 in Removing Heavy Metal Ions, Pb 2+ and Cd 2+, Microporous Mesoporous Mater., 87(3): 163-169 (2006).
[18] Chand R., Narimura K., Kawakita H., Ohto K., Watari T.,  Inoue K., Grape Waste as a Biosorbent for Removing Cr (VI) from Aqueous Solution,
J. Hazard. Mater.
, 163(1): 245-250 (2009).
[19] Chakravarty P., Sarma N.S.,  Sarma H., Biosorption of Cadmium (II) from Aqueous Solution Using Heartwood Powder of Areca Catechu, Chem. Eng. J., 162(3): 949-955 (2010).
[20] Zheng W., Li X.-m., Wang F., Yang Q., Deng P.,  Zeng G.-m., Adsorption Removal of Cadmium and Copper from Aqueous Solution by Areca—A Food Waste, J. Hazard. Mater., 157(2): 490-495 (2008).
[21] Balkaya N.,  Cesur H., Adsorption of Cadmium from Aqueous Solution by Phosphogypsum, Chem. Eng. J., 140(1): 247-254 (2008).
[22] Demirbas A., Heavy Metal Adsorption onto Agro-Based Waste Materials: A Review, J. Hazard. Mater., 157(2): 220-229 (2008).
[23] Sud D., Mahajan G.,  Kaur M., Agricultural Waste Material as Potential Adsorbent for Sequestering Heavy Metal Ions from Aqueous Solutions–A Review, Bioresour. Technol., 99(14): 6017-6027 (2008).
[24] Amarasinghe B.,  Williams R., Tea Waste as a Low Cost Adsorbent for the Removal of Cu and Pb from Wastewater, Chem. Eng. J., 132(1): 299-309 (2007).
 
[26] Srivastava V.C., Mall I.D.,  Mishra I.M., Adsorption Thermodynamics and Isosteric Heat of Adsorption of Toxic Metal Ions onto Bagasse Fly Ash (BFA) and Rice Husk Ash (RHA), Chem. Eng. J., 132(1): 267-278 (2007).
[27] Ishaq M., Saeed K., Ahmad I., Sultan S.,  Akhtar S., Coal Ash as a Low Cost Adsorbent for the Removal of Xylenol Orange from Aqueous Solution, Iran. J. Chem. Chem. Eng.(IJCCE), 33(1): 53-58 (2014).
[28] Sana S., Roostaazad R.,  Yaghmaei S., Biosorption of Uranium (VI) from Aqueous Solution by Pretreated Aspergillus Niger Using Sodium Hydroxide, Iran. J. Chem. Chem. Eng.(IJCCE), 34(1): 65-74 (2015).
[29] Zarrabi M., Noori Sepehr M., Amrollahi M.,  Taghavi M., Biosorption of Fluoride by Apple Pulp from Aqueous Solution, Koomesh, 16(2): 213-219 (2015).
[30] Ghaneian M.T., Jamshidi B., Amrollahi M., Dehvari M., Taghavi M., Application of Biosorption Process by Pomegranate Seed Powder in the Removal of Hexavalent Chromium Fromaqueous Environment, Koomesh, 15(2): 206-211 (2014).
[31] Taghavi M., Zazouli M.A., Yousefi Z.,
Akbari-Adergani B., Kinetic and Isotherm Modeling of Cd (II) Adsorption by l-Cysteine Functionalized Multi-Walled Carbon Nanotubes as Adsorbent, Environ. Monit. Assess., 187(11): 1-10 (2015).
[32] Naseri A., Barati R., Rasoulzadeh F.,  Bahram M., Studies on Adsorption of Some Organic Dyes from Aqueous Solution onto Graphene Nanosheets, Iran. J. Chem. Chem. Eng.(IJCCE), 34(2): 51-60 (2015).
[33] Haq Nawaz B., Rubina K.,  Muhammad Asif H., Biosorption of Pb (II) and Co (II) on Red Rose Waste Biomass, Iran. J. Chem. Chem. Eng.(IJCCE), 30(4): 81-87 (2011).
[34] Mohammad Beigi S., Babapoor A., Maghsoodi V., Mousavi S.M.,  Rajabi N., Batch Equilibrium and Kinetics Studies of Cd (II) Ion Removal from Aqueous Solution Using Porous Chitosan Hydrogel Beads, Iran. J. Chem. Chem. Eng.(IJCCE), 28(3): 81-89 (2009).
[35] Xu H., Liu D.-d., He L., Liu N.,  Ning G., Adsorption of Copper (II) from an Wastewater Effluent of Electroplating Industry by Poly (ethyleneimine)- Functionalized Silica, Iran. J. Chem. Chem. Eng.(IJCCE), 34(2): 73-81 (2015).
[36] Behnamfard A.,  Salarirad M.M., Equilibrium and Kinetic Studies on Free Cyanide Adsorption from Aqueous Solution by Activated Carbon, J. Hazard. Mater., 170(1): 127-133 (2009).