The Catalysis of Ferric Chloride in the Preparation of Graphene Oxide Film

Document Type : Research Article

Authors

1 School of Chemistry and Biological, Engineering, Hechi University, Hechi, 546300, P.R. CHINA

2 Global inquiries and Social Theory Research Group, Ton Duc Thang University, Ho Chi Minh City, VIETNAM

Abstract

Accurate analysis of the catalysis of ferric chloride in the preparation of graphene oxide film can improve the performance of the finished product. The thermal conductivity of graphene film prepared by the original method is low, so a new catalytic analysis method is proposed. Firstly, the flake double-layer graphite oxide is prepared by the improved Hummers method. Under the catalysis of FeC13, different reaction temperatures and reaction times are set to get the finished products of graphene oxide under different conditions. The structure characteristics of the finished products are analyzed, and the structure of that the graphene oxide films prepared at 90℃  and 0.5h is determined to be the best. So far, the catalysis of ferric chloride in the preparation of graphene oxide film has been analyzed. The results show that the thermal conductivity of graphene oxide film prepared by catalysis is 900W/(m.K), which is higher than that of traditional products.

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References

[1] Panpan L.I.U., Hanchao L.I., Lin Y., Ting G.U.O., Peiling K.E., Aiying W., Influence of Annealing Temperature on the Metal-Catalyzed Crystallization of Tetrahedral Amorphous Carbon to Graphene, Chinese J. Mater Res., 32: 341–347 (2018).
[2] Meenakshisundaram V., Hung J-H., Patra T.K., Simmons D.S., Designing Sequence-Specific Copolymer Compatibilizers Using a Molecular-Dynamics-Simulation-Based Genetic Algorithm, Macromolecules, 50: 1155–1166 (2017).
[3] Zhu J., Lai Q., Zhao Y., Zhong J., Liang Y., An Effective FeCl3 Template Assisted Synthesis of Nitrogen, Sulfur and Iron-Tridoped Carbon Nanosheets from a Protic Salt for Oxygen Reduction Electrocatalysis, Chinese J. Catal., 39: 1453–1462 (2018).
[4] Bahrami Adeh N., Mohammadi N., Khorramjah F., Synthesis and Characterization of a Novel Nanoporous Composite Based on Elemental Sulfur and Graphitic Mesoporous Carbon, Iran. J. Chem. Chem. Eng. (IJCCE), 35 (4):1–9 (2016).
[5] Xu H., Gao L., Zhang Q., Li J., Diwu J., Chou X, Tang J., Xue C., Preparation Method of Co3O4 Nanoparticles Using Degreasing Cotton and Their Electrochemical Performances in Supercapacitors, J. Nanomater, 2014; (2014).
[6] He L., Liu J., Liu Y., Cui B., Hu B., Wang M., Tian K., Song Y., Wu S., Zhang Z., Peng Z., Du M., Titanium Dioxide Encapsulated Carbon-Nitride Nanosheets Derived from Mxene and Melamine-Cyanuric Acid Composite as a Multifunctional Electrocatalyst for Hydrogen and Oxygen Evolution Reaction and Oxygen Reduction Reaction,
Appl. Catal. B Environ., 248: 366–279 (2019).
[7] Kutzli I., Gibis M., Baier S.K., Weiss J., Fabrication and Characterization of Food‐Grade Fibers from Mixtures of Maltodextrin and Whey Protein Isolate Using Needleless Electrospinning, J. Appl. Polym. Sci., 135: 46328 (2018).
[8] Wang X., Zhou X., Yao K., Zhang J., Liu Z., A SnO2/graphene Composite as a High Stability Electrode for Lithium Ion Batteries, Carbon N Y, 49:133–139 (2011).
[9] Zhang F., Feng Y., Feng W., Three-Dimensional Interconnected Networks for Thermally Conductive Polymer Composites: Design, Preparation, Properties, and Mechanisms, Mater Sci. Eng. R. Reports, 142: 100580 (2020).
[10] Jing P., Wang Q., Wang B., Gao X., Zhang Y., Wu H., Encapsulating Yolk-Shell FeS2@Carbon Microboxes into Interconnected Graphene Framework for Ultrafast Lithium/Sodium Storage, Carbon N. Y., 159:366–377 (2020).
[11] Zhu W., Dai B., Wu P., Chao Y., Xiong J., Xun S., Li H., Li H., Graphene-Analogue Hexagonal BN Supported with Tungsten-Based Ionic Liquid for Oxidative Desulfurization of Fuels, ACS Sustain Chem. Eng., 3: 186–194 (2015).
[12] He Y., Liu Y., Direct Fabrication Of Highly Porous Graphene/TiO2 Composite Nanofibers by Electrospinning for Photocatalytic Application, J. Cent. South Univ., 25: 2182–2189 (2018).
[13] Monazzam P, Kisomi BF. Co/TiO2 Nanoparticles: Preparation, Characterization and Its Application for Photocatalytic Degradation of Methylene Blue (2017).
[14] Monazzam P., Ebrahimian Pirbazari A., Fakhari B., Khodaee Z., Immobilization of Cobalt Doped Rutile TiO2 on Carbon Nanotubes Walls for Efficient Photodegradation of 2,4-Dichlorophenol under Visible Light. J. Ultrafine Grained Nanostructured Mater, 52:122–132 (2019).

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