In this research, xonotlite was synthesized by a hydrothermal method in the Si-Ca-Na-H2O system. Detailed structural characterization by using the XRD technique revealed that the obtained material contains a small quantity of wollastonite (up to 3 %) as an impurity. Calcination of the obtained sample at 900 ˚C has resulted in a complete transformation of xonotlite to wollastonite which was detected as only a crystal phase. Crystallite size and lattice strain of all crystal phases were calculated using Scherrer and Williamson-Hall method. SEM observation of xonotlite morphology revealed tiny needle-like crystals joined together forming dendritic or globular aggregates. Optimal conditions for electrophoretic deposition of xonotlite on 304-type stainless steel have been achieved by appropriate selection of electric field strengths, dispersing medium, and dispersants. Stable suspension of the material was obtained using isopropanol containing 1 % water as dispersing medium and Ca-nitrate as a charging additive. Native layers of xonotlite have a very smooth morphology, while after calcination, the appearance of small cracks in the coating can be observed but the adhesion strength of the coatings to the substrate is improved.
[1] Mamedov K.S., Belov N.V., Structure of Xonotlite Ca6Si6O17(OH)2, Dokl. Akad. Nauk SSSR, 104: 615- 618 (1955).
[2] Mamedov K.S., Belov N.V., Crystal Structure of the Minerals of the Wollastonite Group. I. Structure of Xonotlite, Zapiski Vserossiiskogo Mineralogicheskogo Obshcesteva, 85: 13-38 (1956).
Čović, J., Jovanović, I., Zarubica, A., Bojic, A., & Randjelovic, M. (2022). Morpho-Structural Characterization and Electrophoretic Deposition of Xonotlite Obtained by a Hydrothermal Method. Iranian Journal of Chemistry and Chemical Engineering, 41(6), 1932-1941. doi: 10.30492/ijcce.2021.131277.4241
MLA
Jelena Čović; Ivana Jovanović; Aleksandra Zarubica; Aleksandar Bojic; Marjan Randjelovic. "Morpho-Structural Characterization and Electrophoretic Deposition of Xonotlite Obtained by a Hydrothermal Method". Iranian Journal of Chemistry and Chemical Engineering, 41, 6, 2022, 1932-1941. doi: 10.30492/ijcce.2021.131277.4241
HARVARD
Čović, J., Jovanović, I., Zarubica, A., Bojic, A., Randjelovic, M. (2022). 'Morpho-Structural Characterization and Electrophoretic Deposition of Xonotlite Obtained by a Hydrothermal Method', Iranian Journal of Chemistry and Chemical Engineering, 41(6), pp. 1932-1941. doi: 10.30492/ijcce.2021.131277.4241
VANCOUVER
Čović, J., Jovanović, I., Zarubica, A., Bojic, A., Randjelovic, M. Morpho-Structural Characterization and Electrophoretic Deposition of Xonotlite Obtained by a Hydrothermal Method. Iranian Journal of Chemistry and Chemical Engineering, 2022; 41(6): 1932-1941. doi: 10.30492/ijcce.2021.131277.4241