Phase Diagrams for Liquid-Liquid Equilibrium of Neopentyl Glycol + Sodium Formate + Water

Document Type : Research Article

Authors

Chemistry and Chemical School, Henan University of Technology, Zhengzhou, P.R. CHINA

Abstract

Phase diagrams for the ternary (neopentyl glycol + sodium formate + water) system were measured. Phase equilibrium data were obtained at different temperatures of 333.15, 343.15, and 353.15 K. The effect of temperature on the liquid–liquid phase equilibrium was studied and the length and slope of the tie-line at different temperatures for the conjugate phase were investigated. It was found that the tie-line length decreases and the two-phase area is slightly reduced by increasing temperature. The three fitting parameters of the Merchuk and Pirdashti equations were obtained with the temperature dependence expressed in the linear form, respectively. Compared with the Pirdashti equation, the binodal curves were described satisfactorily with the Merchuk equation, further, the plait points at various temperatures were estimated by extrapolation. The Othmer-Tobias and Hand models were used for the correlation of the phase equilibrium behavior. The correlation coefficients of the models were obtained for the corresponding temperatures. The results showed that it was well fitted with the Othmer-Tobias model by contrast with the Hand model.

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References

[1] Zhang H., Xu H., Fang X.M., Xu Y.Q., Ding T., Synthesis and Property of a Halogen-Free Flame Retardant Neopentyl Glycol Phenyl Phosphate, Chem. Res., 27(4): 466-469 (2016).
[2] Kamalakar K., Sai Manoj G.N.V.T., Prasad R.B.N., Karuna M.S.L., Novel Acyloxy Derivatives of Branched Mono- and Polyol Esters of Sal Fat: Multiviscosity Grade Lubricant base Stocks, J. Agric. Food Chem., 62(49): 11980-11987 (2014).
[3] Wang M.J., Li Y.W., Zhang X.Y., Sun J., Wang L., Study and Development of Waterborne Acrylic Modified Alkyd Resin, China Coat, 32(3): 57-60 (2017).
[4] Sari A., Alkan C., Bicer A., Development, Characterization, and Latent Heat Thermal Energy Storage Properties of Neopentyl Glycol-Fatty Acid Esters as New Solid–Liquid PCMs, Ind. Eng. Chem. Res., 52(51): 18269-18275 (2013). 
[5] Raof N.A., Yunus R., Rashid U., Azis N., Yaakub Z., Palm-Based Neopentyl Glycol Diester: A Potential Green Insulating Oil, Protein Peptide Lett., 25(2): 171-179 (2018).
[6] Ayush P.S., Sakshum K., Sagar P., Harsh H., Yashkumar P., Bhashin M., Preparation and Characterization of Solid-State Neopentyl Glycol / Expanded Graphite Micro Composite for Thermal Energy Storage Applications, Mater. Today: Proc., 47(2): 621-625 (2020).
[7] Lu J.D., Liu X.J., Yan X.Y., The Analysis of Neopentyl Glycol Market, Chem. Ind., 39(2): 52-56 (2021).
[8] Hao Q.L., Development Analysis of Neopentyl Glycol Industry, Fine Spec. Chem., 25(12): 5-8 (2017).
[9] Pirdashti M., Bozorgzadeh A., Ketabi M., Khoiroh I., Phase Equilibria of Aqueous Mixtures of PEG with Formate Salt: Effects of pH, type of Cation, Polymer Molecular Weight and Temperature, Fluid Phase Equilib., 485(4): 158-167 (2019).
[10] Frolkova A., Zakharova D., Frolkova A., Balbenov S., Liquid–Liquid and Liquid–Liquid Equilibrium for Ternary System Water–Acetonitrile–Cyclohexene at 298.15 K, Fluid Phase Equilib., 408(1): 10-14 (2016).
[11] Yang X.C., Li H.X., Cao C.M., Xu L., Liu G.J., Experimental and Correlated Liquid-Liquid Equilibrium Data for Dimethyl Adipate + 1,6-Hexanediol + Water or Ethylene Glycol, J. Mol. Liq., 284(16): 39-44 (2019).
[12] Ahmadi F., Pirdashti M., Arzideh S.M., Khoiroh I., Phase Behavior for 1-Butyl-3-Methylimidazolium Tetrafluoroborate with Sodium Oxalate/Succinate/Formate Aqueous Two-Phase Systems at 298.15 and 308.15 K, J. Dispers. Sci. Technol., 42(1): 67-74 (2020).
[13] Parmoon G., Nafchi A. M., Pirdashti M., Effects of the Polymer Molecular Weight and Type of Cation on Phase Diagrams of Polythylene Glycol + Sulfate Salts Aqueous Two-Phase Systems, Hem. Ind., 73(6): 375-385 (2019).
[14] Gomis V., Saquete M. D., Font A., García-Cano J., Martínez-Castellanos I., Phase Equilibria of the Water + 1-Butanol + 2-Pentanol Ternary System at 101.3 kPa, J. Chem. Thermodyn., 123(8): 38-45 (2018).
[15] Özmen D., Bekri S., Phase Diagrams for the Aqueous Solutions of Carboxylic Acid with Dipropyl Ether: Experimental and Correlated Data, Iran. J. Chem. Chem. Eng. (IJCCE), 39(6): 173-183 (2020).
[16] Parab P., Bhagwat S., Thermophysical Properties of Ternary Systems Potassium Formate + Propylene Glycol/Glycerol + Water, J. Chem. Eng. Data, 64(1): 234-244 (2019).
[17] Parmoona G., Nafchib A.M., Pirdashti M., Density, Viscosity, Refractive Index and Excess Properties of Binary and Ternary Solutions of Poly (Ethylene Glycol), Sulfate Salts and Water at 298.15 K, Phys. Chem. Res., 7(4): 859-884 (2019).
[18] Ghanadzadeh Gilani A., Ahmadifar S., Taki T., Experimental and Modeling Study of Liquid Phase Equilibria for (Water + Phosphoric Acid + Sec-Alcohols) Systems, J. Chem. Thermodyn., 135(8): 305-315 (2019).
[19] Ahmadi F., Pirdashti M., Rostami A.A., Density, Refractive Index And Liquid–Liquid Equilibrium Data Of Polyethylene Glycol 3000 + Potassium Formate + Water at Different pH Values, Chin. J. Chem. Eng., 26(1): 168-174 (2018).
[20] Reggab S., Merzougui A., Hassiene A., Qjemoui L., Bouredji H., Experimental Data and Modeling of Salt Effect on Liquid-Liquid Equilibrium of the Ternary (Water+1-Propanol+Hexane) System at 298K, Iran. J. Chem. Chem. Eng. (IJCCE), 39(6):199-209 (2020).
[21] Sadeghi B.，Ghamami S., Bimetallic Ag/Co synthesized at liquid/liquid interface with controllable core/shell structures， Chem. Eng. Commun., 200(2): 178-184 (2013).
[22] Kong H., Li P., Song Z.D., Zhang Z.Y., Wang Y.F., Liquid-Liquid Equilibria of Ternary Systems Water+ PODE1/PODE2 + Extractants, J. Chem. Eng. Chin. Univ., 34(1): 27-33 (2020).
[23] Arzideh S.M., Nateri M.S., Pirdashti M., Temperature, Polymer Molecular Weight, and Salt Effects on Phase Equilibria of PVP + Formate Salts + Water: Experimental Measurements, Correlations, and Thermodynamic Modeling, J. Chem. Eng. Data, 66(12): 4496-4507 (2021).
[24] Huang Q., Yu X.D., Li M.L., Zheng H., Zeng Y., Experimental and Thermodynamic Simulation for Ternary Systems KCl+PEG10000/20000+ H2O at 308.2 K, J. Chem. Eng., 72(4): 1895-1905 (2021).
[25] Sa E.J., Lee B.S., Park B. H., Extraction of Ethanol from Mixtures with n-Hexane by Deep Eutectic Solvents of Choline Chloride + Levulinic Acid, + Ethylene Glycol, or + Malonic Acid, J. Mol. Liq., 316(10): 113877-113882 (2020).
[26] Cavalcanti K.V.M., Follegatti-Romero L.M., Dalmolin I., Follegatti-Romeroa L. A., Liquid-Liquid Equilibrium for (Water + 5-Hydroxymethylfurfural + 1-Pentanol/1-Hexanol/1-Heptanol) Systems at 298.15 K, J. Chem. Thermodyn., 138(11): 59-66 (2019).
[27] Liu Y., Wang Y., Wang F.C., Salting Effect of Sodium Hydroxide and Sodium Formate on the Liquid–Liquid Equilibrium of Polyoxymethylene Dimethyl Ethers in Aqueous Solution, J. Chem. Eng. Data, 64(6): 2578-2592 (2019).
Iranian Journal of Chemistry and Chemical Engineering
Volume 41, Issue 12 - Serial Number 122
December 2022
Pages 4228-4233

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