Mineralogical and Physicochemical Characterization of Enugu Iva-Pottery Silica-Rich Deposit for Ceramics Applications

Document Type : Research Article

Authors

1 Ceramic Research and Production Department, Projects Development Institute (PRODA), Enugu, NIGERIA

2 Department of Pure and Industrial Ceramic Research and Production Department, Projects Development Institute (PRODA), Enugu, NIGERIA

3 Engineering Research Development and Production Department, Project Development Institute (PRODA), Enugu, NIGERIA

Abstract

The exploration of indigenous raw materials that are pure and simple to process for ceramics is a scalable option for locally-made ceramics products. This study involves the characterization of unexplored silica-rich sand deposits at Iva-pottery, Enugu North local government area in Enugu state Nigeria for their ceramic industrial potential. The physicochemical properties of Iva-pottery silica-rich sand were determined. The crystalline phase components and elemental compositions of the oxide were investigated with an X-ray diffractometer and an X-ray fluorescence spectrophotometer respectively. The silica was used in ceramics composition as a filler and glaze formulation as glass former.  The results obtained showed mainly a siliceous crystalline phase with a minor amorphous phase and contains 74.55% SiO2, 13.02% Al2O3, and 0.55% Fe. The grain size in the raw form is in the range of 0.18 mm to 0.075 mm (100 mesh to + 200 mesh range) without involving ceramic raw materials processing equipment such as a ball mill as well as a high percentage of alumina (13.02) contents as compared to conventional silica with alumina 0.02% to 0.5% range. The high alumina that forms mullite at sintering temperature brings about a low thermal coefficient and hence, suitable chemical stability and resistance to thermal shock.  These rare qualities make the Iva-pottery silica-rich sand an emergent material suitable for glaze formulation and filler in ceramic bodies. Thus, it is recommended that the Iva-pottery silica-rich sand deposits in their raw form be exploited for the formulation of varied glaze temperature ranges and also for the refractory industry. Iva-pottery silica-rich deposits in their raw form, do not meet the requirements of high tech- ceramics applications.

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References

[1] Adelabu O.S., Ologunwa T.P., Akinbogun T.L. Challenges of Glazed-Ceramics Production in Nigeria, ASHA. J. Ceram., (10): 43-47( 2013)
[2] Stevens S.J., Hand R.J., Sharp J.H., Polymorphism of Silica,  J. Mater. Sc., 32: 28-29 (1997).
[3] ] Edem C.A., Malu S.P., Ita B.I., Characterization and Beneficiation of the Glass Making Potentials of Silica Sand Deposit from River Benue North-Central Nigeria, J. Nat. Sci. Res., 4(19): 2224-3186 (1993).
[4] Platias S., Vatalis K.I., Charalampides G,. Suitability of Quartz Sands for Different Industrial Applications, Int.Conf. Appl. Econ., (14): 491-498 (2014).
[5] Malu S.P., Bassey G.A., Periwinkle (T. Fuscatus) Shell as an Alternative Source of Lime for the Glass Industry, Glo. J. Pu. Appl. Sci., (4): 491-494 (2003)
[6] Alemaka E.M., Garkida A.D., Abdullahi A.M., Characterization of Makkoda Silica Sand Deposit in Kano State Northwest Nigeria for Use in Glass Manufacturing, J. Sci. Tech. Edu, 9(2): 131-138 (2021).
[7] Adindu C. Iyasara, Moses Joseph, Thaddeus E. Azubuike, Tse Daniel T. Exploring Ceramic Raw Materials In Nigeria and Their Contribution to the Nation’s Development, Am. J. Eng. Res. (AJER), 3(9): 127-134 (2014)
[8] Müller A., Wanvik J.E., Ihlen P.M., Petrological and Chemical Characterization of High-Purity Quartz Deposits with Examples from Norway, Springer Geology, 71–118 (2012)
[9] Ebeigbe S., Omem I., Addressing the Ceramics Studio Equipment Challenge in Nigeria: Utilizing Re-Used Materials for the Production of a Ball Mill Jar, EJOTMAS Ekpoma J. Thea.  Med. Arts., 5:1-2(2016).
[10] Ekpunobi E.U., Agbo S.C., Ajiwe V.I.E., Evaluation of the Mixtures of Clay, Diatomite, and Sawdust for Production of Ceramic Pot Filters for Water Treatment Interventions Using Locally Sourced Materials, J. En. Chem. Eng. (JECE), 7(1): 2213-3437(2019).
[11] Kimambo Vivian, Joseph Yoeza Naimani Philip, Ester Hellen Lugwisha, Suitability of Tanzanian Kaolin, Quartz and Feldspar as Raw Materials for the Production of Porcelain Tiles, Int. J. of Sci. Techno.Soc., 6(2): 201-209(2014)
[12] Nnaneme F.O., Onuegbu T.U., Agbo S.C., Okwute E.S., The Characterization of Local Clay from Anambra State Nigeria for its Potential Applications in the Production of Ceramic Whitewares, Asian J. Chem Sci., 8(2): 22-33( 2020)
[13] Akwilapo L.D., Wiik, K. Ceramic Properties of Pugu Kaolin Clays. Part I: Porosity and Modulus of Rupture, Bull, Chem. Soc. Ethiop., 17(2): 147–154 (2014).
[14] Lawal A.O., Abdullahi Y., Evaluation of Industrial Potentials of Alluvial Clays from the Confluence of Rivers Niger and Mimi, Sci. Wor. J., 5(3): 213-22 (2010).
[15] Anghelescu Lucica, Mihai Cruceru, Bruno Valentim, and Bogdan Diaconu., Coal Ash Inorganic Residue as Raw Material for Construction Elements. International Journal of Chemistry and Chemical Engineering Systems 3 (2018).
[16] Salah Ben, Imed, M’barek Jemaii, Moufida, Sdiri, Ali, Boughdiri, Mabrouk, Karoui, Narjess.  Chemical and Technological Characterization and Beneficiation of Jezza Sand (North West Of Tunisia): Potentialities of Use in the Industrial Field, Int. J. Min. Proc., (2016).
[17] Duvuna G.A., Ayuba A., A Study on Silica Sand Quality in Yazaram and Mugulbu Deposit for Glass Making, Nig. J. Techn (NIJOTECH), 34(1): 109-112 (2015).
[18] Binti Zakri H., Binti Hussin A., The Potential of Quartz Rock at Kg. Padang Biawas, Negeri Sembilan for Solar Silicon Application, Am. Inst. Phy., 1571: (2013); AIP Conference Proceedings.
[19] Hunt J.M., Wisherd M.P., Bonham L.C., Infrared Absorption Spectra of Minerals and other Inorganic Compounds, Anal. Chem., 19(50):1478-1497 (1950).
[20] Farmer V.C. “Infrared Spectra of Minerals”. Mineralogical Society, Monograph, London. 1149–1173 (1974).
[21] Manoharan C., Sutharsan  P., Dhanapandian S., Venkatachalapathy R., Spectroscopic and Thermal Analysis of Red Clay for Industrial Applications From Tamilnadu, Ind. J. Mol.Str, 27(10): 99–103 (2012).
[22] Li W., Xu Ch., Xie A., Chen K., Yang Y., Liu L., Zhu Sh., Microstructure Study of Phase Transformation of Quartz in Potassium Silicate Glass at 900 °C and 1000 °C, Crystals, 11: 1481 (2021).
[23] Rashed. A.I., Chana Y.C., Fakhrul M.I., Structure-Property Relationship in High-Tension Ceramic Insulator Fired at High Temperature, Mater. Sci. Eng. B., 106(2): 132-140 (2004);
[24] Dana K., Sinhamahapatra S., Sekhar Tripathi H., Ghosh A., Refractories of Alumina-Silica System, Transactions of the Indian Ceramic Society, 73: 1-13 (2014).
Iranian Journal of Chemistry and Chemical Engineering
Volume 42, Issue 1 - Serial Number 123
January 2023
Pages 100-110

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